1. Phoebe: What's the matter?
Rachel: I'm just bummed about the way I left things with Ross. I shouldn't have lied to him about having to work. He seemed so mad at me.
Phoebe: Eh, don't be so hard on yourself. If someone I was still in love with was getting married...
Rachel: (interrupting) Still in love with?!
Phoebe: Yeah!
Rachel: I'm not in love with Ross!
Phoebe: Oh. No. No. Good! Yeah, me neither.
Rachel: Phoebe, I'm going to Ross's wedding because he is my ex-boyfriend and that would be really uncomfortable. Not because, I'm still in love with him! I mean, hey, y'know, I like Ross as much as the next guy, y'know? Clearly I have feelings for him, but feelings don't mean love! I mean, I still have loving feelings for Ross. Yeah! But, I have, I have continuing feelings of love, but that doesn't mean that-that I'm still in love with him. Y'know? I-I have sexual feelings for him, but I do love him-Ohh! Oh my God! Oh my-why didn't you tell me?!!
Phoebe: We thought you knew!

2. Phoebe: So? Did you get the annulment?
Ross: I couldn’t.
Phoebe: I knew it! Because you love Rachel.
Ross: It’s not that. Okay? Annulments are more complicated than I…
Phoebe: Yeah, complicated ‘cause of the love.
Ross: I… I do, I do not love Rachel. I’m gonna tell her right now about the whole thing so we can get this marriage annulled as fast as possible. Okay? Would I do that if I loved her?
Phoebe: I’ve never been more convinced of your love for her.

this one was funny

Phoebe is the ultimate Ross&Rachel shipper and I love her for that (!!!) haha ,I mean she's their biggest fan -after me :P- . Anyway I love this moment!